By Vladimir Ya. Lee,Akira Sekiguchi
Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb describes the chemistry of this fascinating new category of organometallics, with an emphasis on their significant similarities and adjustments with the analogous species in natural chemistry. themes coated comprise comprise the synthesis, constitution, reactions and artificial functions of :
- Si-, Ge-, Sn and Pb-centered cations, radicals and anions
- heavy analogues of carbenes: silylenes, germylenes, stannylenes and plumbylenes
- heavy analogues of alkenes: disilenes, digermenes, distannenes, diplumbenes
- heavy analogues of alkynes: disilynes, digermynes, distannynes, diplumbynes, and their valence isomers
- heteronuclear derivatives: silenes, germenes, stannenes, silagermenes, silastannenes, germastannenes
- heavy analogues of alkenes of the sort: >E14=E13-, >E14=E15-, >E14=E16 [where E13, E14, E15 and E16 are components of the teams thirteen, 14, 15 and 16]
- cyclic compounds (three-, four-, five-, and 6-membered rings)
- heavy analogues of 1,3-dienes, allenes and different cumulenes
- heavy analogues of fragrant compounds; together with a comparability among organometallic and natural aromaticity
Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb is an important consultant to this rising type of organometallic reagents for researchers and scholars in major staff, organometallic, man made and silicon chemistry
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Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb: From Phantom Species to Stable Compounds by Vladimir Ya. Lee,Akira Sekiguchi
by Brian
4.4
